{"id":12208,"date":"2025-07-16T18:21:47","date_gmt":"2025-07-16T10:21:47","guid":{"rendered":"https:\/\/www.zuheliao.com\/index.php\/archives\/12208"},"modified":"2025-07-16T18:21:47","modified_gmt":"2025-07-16T10:21:47","slug":"%e5%af%b9%e6%af%94%e4%b8%8d%e5%90%8c%e7%bb%93%e6%9e%84%e6%9c%89%e6%9c%ba%e8%83%ba%e5%82%ac%e5%8c%96%e5%89%82%e5%8f%8a%e4%b8%ad%e9%97%b4%e4%bd%93%e5%9c%a8%e5%82%ac%e5%8c%96%e6%80%a7%e8%83%bd%e5%92%8c","status":"publish","type":"post","link":"https:\/\/www.zuheliao.com\/index.php\/archives\/12208","title":{"rendered":"\u5bf9\u6bd4\u4e0d\u540c\u7ed3\u6784\u6709\u673a\u80fa\u50ac\u5316\u5242\u53ca\u4e2d\u95f4\u4f53\u5728\u50ac\u5316\u6027\u80fd\u548c\u5e94\u7528\u7279\u70b9\u4e0a\u7684\u5dee\u5f02"},"content":{"rendered":"<p>\u6807\u9898\uff1a\u6709\u673a\u80fa\u50ac\u5316\u5242\u7684\u201c\u6c5f\u6e56\u201d\uff1a\u8c01\u624d\u662f\u771f\u6b63\u7684\u201c\u50ac\u5316\u5927\u5e08\u201d\uff1f<\/p>\n<hr \/>\n<h3>\u5f15\u8a00\uff1a\u50ac\u5316\u5242\u7684\u4e16\u754c\uff0c\u4e0d\u53ea\u662f\u91d1\u5c5e\u7684\u5929\u4e0b<\/h3>\n<p>\u63d0\u5230\u50ac\u5316\u5242\uff0c\u5f88\u591a\u4eba\u7b2c\u4e00\u53cd\u5e94\u662f\u8d35\u91d1\u5c5e\u94c2\u3001\u94af\u3001\u954d\u4e4b\u7c7b\u7684\u91d1\u5c5e\u3002\u4f46\u5176\u5b9e\uff0c\u5728\u6709\u673a\u5408\u6210\u7684\u6c5f\u6e56\u4e2d\uff0c\u6709\u673a\u80fa\u50ac\u5316\u5242\u65e9\u5df2\u6084\u7136\u5d1b\u8d77\uff0c\u6210\u4e3a\u4e0d\u53ef\u6216\u7f3a\u7684\u201c\u5e55\u540e\u82f1\u96c4\u201d\u3002\u5b83\u4eec\u4e0d\u50cf\u91d1\u5c5e\u50ac\u5316\u5242\u90a3\u6837\u5f20\u626c\uff0c\u5374\u4ee5\u6e29\u548c\u3001\u9ad8\u6548\u3001\u73af\u4fdd\u7684\u7279\u6027\u5728\u8bb8\u591a\u53cd\u5e94\u4e2d\u5927\u653e\u5f02\u5f69\u3002<\/p>\n<p>\u6709\u673a\u80fa\u50ac\u5316\u5242\u79cd\u7c7b\u7e41\u591a\uff0c\u7ed3\u6784\u5404\u5f02\uff0c\u4ece\u7b80\u5355\u7684\u4e09\u4e59\u80fa\u5230\u590d\u6742\u7684\u812f\u6c28\u9178\u884d\u751f\u7269\uff0c\u6bcf\u4e00\u79cd\u90fd\u6709\u5176\u72ec\u7279\u7684\u201c\u6027\u683c\u201d\u548c\u201c\u672c\u9886\u201d\u3002\u672c\u6587\u5c06\u5e26\u4f60\u8d70\u8fdb\u6709\u673a\u80fa\u50ac\u5316\u5242\u7684\u4e16\u754c\uff0c\u770b\u770b\u5b83\u4eec\u662f\u5982\u4f55\u5728\u50ac\u5316\u53cd\u5e94\u4e2d\u5404\u663e\u795e\u901a\u7684\u3002<\/p>\n<hr \/>\n<h3>\u4e00\u3001\u6709\u673a\u80fa\u50ac\u5316\u5242\u7684\u57fa\u672c\u201c\u6027\u683c\u201d<\/h3>\n<p>\u6709\u673a\u80fa\u50ac\u5316\u5242\u662f\u6307\u542b\u6709\u6c2e\u539f\u5b50\u7684\u6709\u673a\u5316\u5408\u7269\uff0c\u80fd\u591f\u901a\u8fc7\u63d0\u4f9b\u5b64\u5bf9\u7535\u5b50\u6765\u4fc3\u8fdb\u53cd\u5e94\u8fdb\u884c\u3002\u5b83\u4eec\u5e7f\u6cdb\u5e94\u7528\u4e8e\u4eb2\u6838\u53d6\u4ee3\u3001\u4eb2\u6838\u52a0\u6210\u3001\u6c27\u5316\u8fd8\u539f\u3001\u4e0d\u5bf9\u79f0\u50ac\u5316\u7b49\u591a\u79cd\u53cd\u5e94\u7c7b\u578b\u3002<\/p>\n<p>\u6839\u636e\u7ed3\u6784\u4e0d\u540c\uff0c\u5e38\u89c1\u7684\u6709\u673a\u80fa\u50ac\u5316\u5242\u5927\u81f4\u53ef\u5206\u4e3a\u4ee5\u4e0b\u51e0\u7c7b\uff1a<\/p>\n<table>\n<thead>\n<tr>\n<th>\u7c7b\u578b<\/th>\n<th>\u4ee3\u8868\u5316\u5408\u7269<\/th>\n<th>\u5e38\u89c1\u7528\u9014<\/th>\n<th>\u50ac\u5316\u7279\u70b9<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u4f2f\u80fa\u7c7b<\/td>\n<td>\u82ef\u80fa\u3001\u4e59\u80fa<\/td>\n<td>\u9170\u5316\u53cd\u5e94\u3001\u7f29\u5408\u53cd\u5e94<\/td>\n<td>\u53cd\u5e94\u6e29\u548c\uff0c\u9009\u62e9\u6027\u4e00\u822c<\/td>\n<\/tr>\n<tr>\n<td>\u4ef2\u80fa\u7c7b<\/td>\n<td>\u4e8c\u4e59\u80fa\u3001<\/td>\n<td>\u4eb2\u6838\u53d6\u4ee3\u3001\u6c27\u5316\u53cd\u5e94<\/td>\n<td>\u6d3b\u6027\u8f83\u5f3a\uff0c\u9002\u7528\u8303\u56f4\u5e7f<\/td>\n<\/tr>\n<tr>\n<td>\u53d4\u80fa\u7c7b<\/td>\n<td>\u4e09\u4e59\u80fa\u3001DABCO<\/td>\n<td>\u9178\u4e2d\u548c\u3001Michael\u52a0\u6210<\/td>\n<td>\u78b1\u6027\u5f3a\uff0c\u9002\u5408\u8d28\u5b50\u8f6c\u79fb\u53cd\u5e94<\/td>\n<\/tr>\n<tr>\n<td>\u6742\u73af\u80fa\u7c7b<\/td>\n<td>\u5421\u5576\u3001\u55b9\u5549<\/td>\n<td>\u6c27\u5316\u3001\u8fd8\u539f\u3001\u5076\u8054\u53cd\u5e94<\/td>\n<td>\u7ed3\u6784\u7a33\u5b9a\uff0c\u50ac\u5316\u6d3b\u6027\u9ad8<\/td>\n<\/tr>\n<tr>\n<td>\u4e0d\u5bf9\u79f0\u80fa\u7c7b<\/td>\n<td>\u812f\u6c28\u9178\u3001TBD<\/td>\n<td>\u4e0d\u5bf9\u79f0\u5408\u6210\u3001\u624b\u6027\u63a7\u5236<\/td>\n<td>\u624b\u6027\u8bf1\u5bfc\u80fd\u529b\u5f3a\uff0c\u4ea7\u7387\u9ad8<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<hr \/>\n<h3>\u4e8c\u3001\u4e0d\u540c\u7ed3\u6784\u6709\u673a\u80fa\u50ac\u5316\u5242\u7684\u201c\u7edd\u6d3b\u201d\u89e3\u6790<\/h3>\n<h4>1. \u4e09\u4e59\u80fa\uff08TEA\uff09\u2014\u2014\u201c\u50ac\u5316\u5242\u754c\u7684\u4e07\u91d1\u6cb9\u201d<\/h4>\n<p>\u4e09\u4e59\u80fa\u662f\u5e38\u89c1\u7684\u53d4\u80fa\u7c7b\u50ac\u5316\u5242\u4e4b\u4e00\uff0c\u7ed3\u6784\u7b80\u5355\uff0c\u4ef7\u683c\u4f4e\u5ec9\uff0c\u5e7f\u6cdb\u7528\u4e8e\u6709\u673a\u5408\u6210\u4e2d\u4f5c\u4e3a\u78b1\u6216\u50ac\u5316\u5242\u3002<\/p>\n<p><strong>\u5e94\u7528\u4e3e\u4f8b\uff1a<\/strong><\/p>\n<ul>\n<li><strong>\u9170\u5316\u53cd\u5e94<\/strong>\uff1a\u5728\u916f\u5316\u3001\u9170\u6c2f\u5408\u6210\u4e2d\uff0c\u4e09\u4e59\u80fa\u53ef\u4e2d\u548c\u751f\u6210\u7684HCl\uff0c\u63a8\u52a8\u53cd\u5e94\u8fdb\u884c\u3002<\/li>\n<li><strong>Michael\u52a0\u6210<\/strong>\uff1a\u4f5c\u4e3a\u6c22\u8f6c\u79fb\u50ac\u5316\u5242\uff0c\u5e2e\u52a9\u4eb2\u6838\u8bd5\u5242\u8fdb\u653b\u03b1,\u03b2-\u4e0d\u9971\u548c\u4f53\u7cfb\u3002<\/li>\n<\/ul>\n<p><strong>\u4f18\u70b9\uff1a<\/strong><\/p>\n<ul>\n<li>\u6210\u672c\u4f4e\uff0c\u6613\u5f97<\/li>\n<li>\u78b1\u6027\u5f3a\uff0c\u9002\u5408\u4e2d\u548c\u9178\u6027\u526f\u4ea7\u7269<\/li>\n<\/ul>\n<p><strong>\u7f3a\u70b9\uff1a<\/strong><\/p>\n<ul>\n<li>\u6613\u6325\u53d1\uff0c\u6c14\u5473\u523a\u9f3b<\/li>\n<li>\u50ac\u5316\u80fd\u529b\u4e00\u822c\uff0c\u96be\u4ee5\u80dc\u4efb\u9ad8\u96be\u5ea6\u53cd\u5e94<\/li>\n<\/ul>\n<h4>2. DABCO\uff081,4-\u4e8c\u6c2e\u6742\u4e8c\u73af[2.2.2]\u8f9b\u70f7\uff09\u2014\u2014\u201c\u4eb2\u6838\u53cd\u5e94\u7684\u9ad8\u624b\u201d<\/h4>\n<p>DABCO\u662f\u4e00\u79cd\u5f3a\u78b1\u6027\u3001\u521a\u6027\u7ed3\u6784\u7684\u6742\u73af\u80fa\uff0c\u5e38\u7528\u4e8e\u4fc3\u8fdb\u4eb2\u6838\u52a0\u6210\u3001\u73af\u6c27\u5316\u7269\u5f00\u73af\u7b49\u53cd\u5e94\u3002<\/p>\n<p><strong>\u5e94\u7528\u4e3e\u4f8b\uff1a<\/strong><\/p>\n<ul>\n<li><strong>\u73af\u6c27\u5f00\u73af\u53cd\u5e94<\/strong>\uff1aDABCO\u80fd\u6709\u6548\u50ac\u5316\u73af\u6c27\u4e0e\u9187\u3001\u80fa\u7b49\u4eb2\u6838\u8bd5\u5242\u7684\u5f00\u73af\u3002<\/li>\n<li><strong>Michael\u52a0\u6210<\/strong>\uff1a\u6bd4\u4e09\u4e59\u80fa\u66f4\u9ad8\u6548\uff0c\u5c24\u5176\u5728\u4f4e\u6e29\u4e0b\u8868\u73b0\u4f18\u5f02\u3002<\/li>\n<\/ul>\n<p><strong>\u4f18\u70b9\uff1a<\/strong><\/p>\n<ul>\n<li>\u50ac\u5316\u6d3b\u6027\u9ad8<\/li>\n<li>\u7ed3\u6784\u7a33\u5b9a\uff0c\u8010\u9ad8\u6e29<\/li>\n<\/ul>\n<p><strong>\u7f3a\u70b9\uff1a<\/strong><\/p>\n<ul>\n<li>\u6210\u672c\u76f8\u5bf9\u8f83\u9ad8<\/li>\n<li>\u5728\u6c34\u4e2d\u6613\u5206\u89e3\uff0c\u9700\u63a7\u5236\u53cd\u5e94\u6761\u4ef6<\/li>\n<\/ul>\n<h4>3. \u5421\u5576\u53ca\u5176\u884d\u751f\u7269\u2014\u2014\u201c\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u7684\u5e38\u5ba2\u201d<\/h4>\n<p>\u5421\u5576\u662f\u5178\u578b\u7684\u6742\u73af\u80fa\u7c7b\u50ac\u5316\u5242\uff0c\u5176\u82b3\u9999\u6027\u7ed3\u6784\u8d4b\u4e88\u5176\u826f\u597d\u7684\u7a33\u5b9a\u6027\u548c\u50ac\u5316\u6d3b\u6027\u3002<\/p>\n<p><strong>\u5e94\u7528\u4e3e\u4f8b\uff1a<\/strong><\/p>\n<ul>\n<li><strong>\u6c27\u5316\u53cd\u5e94<\/strong>\uff1a\u5982Jones\u6c27\u5316\u3001Swern\u6c27\u5316\u4e2d\u4f5c\u4e3a\u78b1\u6216\u914d\u4f53\u3002<\/li>\n<li><strong>\u4eb2\u6838\u53d6\u4ee3<\/strong>\uff1a\u4fc3\u8fdbSN2\u53cd\u5e94\uff0c\u5c24\u5176\u5728\u6781\u6027\u6eb6\u5242\u4e2d\u6548\u679c\u663e\u8457\u3002<\/li>\n<\/ul>\n<p><strong>\u4f18\u70b9\uff1a<\/strong><\/p>\n<ul>\n<li>\u6eb6\u89e3\u6027\u597d\uff0c\u9002\u7528\u4e8e\u591a\u79cd\u6eb6\u5242<\/li>\n<li>\u50ac\u5316\u6548\u7387\u9ad8\uff0c\u9002\u5408\u5de5\u4e1a\u5e94\u7528<\/li>\n<\/ul>\n<p><strong>\u7f3a\u70b9\uff1a<\/strong><\/p>\n<ul>\n<li>\u6bd2\u6027\u8f83\u9ad8\uff0c\u64cd\u4f5c\u9700\u6ce8\u610f\u5b89\u5168<\/li>\n<li>\u6613\u4e0e\u91d1\u5c5e\u5f62\u6210\u914d\u5408\u7269\uff0c\u5f71\u54cd\u53cd\u5e94\u8def\u5f84<\/li>\n<\/ul>\n<h4>4. \u812f\u6c28\u9178\u53ca\u5176\u884d\u751f\u7269\u2014\u2014\u201c\u4e0d\u5bf9\u79f0\u5408\u6210\u7684\u738b\u8005\u201d<\/h4>\n<p>\u812f\u6c28\u9178\u662f\u7b80\u5355\u7684\u5929\u7136\u624b\u6027\u80fa\u7c7b\u50ac\u5316\u5242\uff0c\u5e7f\u6cdb\u7528\u4e8e\u4e0d\u5bf9\u79f0\u5408\u6210\u4e2d\uff0c\u5982Aldol\u53cd\u5e94\u3001Mannich\u53cd\u5e94\u7b49\u3002<\/p>\n<p><img decoding=\"async\" src=\"\/images\/59.jpg\" alt=\"\"><\/p>\n<ul>\n<li>\u6bd2\u6027\u8f83\u9ad8\uff0c\u64cd\u4f5c\u9700\u6ce8\u610f\u5b89\u5168<\/li>\n<li>\u6613\u4e0e\u91d1\u5c5e\u5f62\u6210\u914d\u5408\u7269\uff0c\u5f71\u54cd\u53cd\u5e94\u8def\u5f84<\/li>\n<\/ul>\n<h4>4. \u812f\u6c28\u9178\u53ca\u5176\u884d\u751f\u7269\u2014\u2014\u201c\u4e0d\u5bf9\u79f0\u5408\u6210\u7684\u738b\u8005\u201d<\/h4>\n<p>\u812f\u6c28\u9178\u662f\u7b80\u5355\u7684\u5929\u7136\u624b\u6027\u80fa\u7c7b\u50ac\u5316\u5242\uff0c\u5e7f\u6cdb\u7528\u4e8e\u4e0d\u5bf9\u79f0\u5408\u6210\u4e2d\uff0c\u5982Aldol\u53cd\u5e94\u3001Mannich\u53cd\u5e94\u7b49\u3002<\/p>\n<p><strong>\u5e94\u7528\u4e3e\u4f8b\uff1a<\/strong><\/p>\n<ul>\n<li><strong>Aldol\u53cd\u5e94<\/strong>\uff1a\u5728\u4e0d\u5bf9\u79f0\u6761\u4ef6\u4e0b\uff0c\u812f\u6c28\u9178\u53ef\u8bf1\u5bfc\u9ad8\u5bf9\u6620\u9009\u62e9\u6027\u3002<\/li>\n<li><strong>Mannich\u53cd\u5e94<\/strong>\uff1a\u901a\u8fc7\u4e9a\u80fa\u4e2d\u95f4\u4f53\u5b9e\u73b0\u624b\u6027\u63a7\u5236\u3002<\/li>\n<\/ul>\n<p><strong>\u4f18\u70b9\uff1a<\/strong><\/p>\n<ul>\n<li>\u624b\u6027\u8bf1\u5bfc\u80fd\u529b\u5f3a<\/li>\n<li>\u53cd\u5e94\u6761\u4ef6\u6e29\u548c\uff0c\u7eff\u8272\u53cb\u597d<\/li>\n<\/ul>\n<p><strong>\u7f3a\u70b9\uff1a<\/strong><\/p>\n<ul>\n<li>\u50ac\u5316\u6548\u7387\u53d7\u6eb6\u5242\u548c\u6e29\u5ea6\u5f71\u54cd\u5927<\/li>\n<li>\u5bf9\u67d0\u4e9b\u5e95\u7269\u9002\u5e94\u6027\u6709\u9650<\/li>\n<\/ul>\n<h4>5. TBD\uff081,5,7-\u4e09\u6c2e\u6742\u53cc\u73af[4.4.0]\u7678-5-\u70ef\uff09\u2014\u2014\u201c\u8d85\u5f3a\u78b1\uff0c\u9ad8\u6d3b\u6027\u201d<\/h4>\n<p>TBD\u662f\u4e00\u79cd\u8d85\u5f3a\u78b1\u6027\u7684\u6709\u673a\u80fa\u50ac\u5316\u5242\uff0c\u5c24\u5176\u9002\u7528\u4e8e\u8d28\u5b50\u8f6c\u79fb\u56f0\u96be\u7684\u53cd\u5e94\u3002<\/p>\n<p><strong>\u5e94\u7528\u4e3e\u4f8b\uff1a<\/strong><\/p>\n<ul>\n<li><strong>\u916f\u4ea4\u6362\u53cd\u5e94<\/strong><\/li>\n<li><strong>Knoevenagel\u7f29\u5408<\/strong><\/li>\n<li><strong>Stille\u5076\u8054\u4e2d\u7684\u78b1\u52a9\u5242<\/strong><\/li>\n<\/ul>\n<p><strong>\u4f18\u70b9\uff1a<\/strong><\/p>\n<ul>\n<li>\u78b1\u6027\u6781\u5f3a\uff0c\u9002\u5408\u96be\u53cd\u5e94\u4f53\u7cfb<\/li>\n<li>\u50ac\u5316\u6d3b\u6027\u9ad8\uff0c\u7528\u91cf\u5c11<\/li>\n<\/ul>\n<p><strong>\u7f3a\u70b9\uff1a<\/strong><\/p>\n<ul>\n<li>\u6210\u672c\u9ad8\u6602<\/li>\n<li>\u5bf9\u7a7a\u6c14\u548c\u6c34\u5206\u654f\u611f\uff0c\u9700\u4e25\u683c\u50a8\u5b58<\/li>\n<\/ul>\n<hr \/>\n<h3>\u4e09\u3001\u4e2d\u95f4\u4f53\u7684\u201c\u50ac\u5316\u5242\u4eba\u751f\u201d<\/h3>\n<p>\u5728\u6709\u673a\u80fa\u50ac\u5316\u8fc7\u7a0b\u4e2d\uff0c\u4e2d\u95f4\u4f53\u7684\u5f62\u6210\u548c\u7a33\u5b9a\u6027\u5bf9\u50ac\u5316\u6548\u7387\u81f3\u5173\u91cd\u8981\u3002\u5e38\u89c1\u7684\u4e2d\u95f4\u4f53\u5305\u62ec\uff1a<\/p>\n<table>\n<thead>\n<tr>\n<th>\u50ac\u5316\u5242\u7c7b\u578b<\/th>\n<th>\u5178\u578b\u4e2d\u95f4\u4f53<\/th>\n<th>\u5f62\u6210\u673a\u5236<\/th>\n<th>\u5bf9\u53cd\u5e94\u7684\u5f71\u54cd<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u812f\u6c28\u9178<\/td>\n<td>\u4e9a\u80fa\/\u70ef\u80fa\u4e2d\u95f4\u4f53<\/td>\n<td>\u4e0e\u7fb0\u57fa\u5316\u5408\u7269\u7f29\u5408<\/td>\n<td>\u63d0\u9ad8\u624b\u6027\u63a7\u5236\u80fd\u529b<\/td>\n<\/tr>\n<tr>\n<td>\u5421\u5576<\/td>\n<td>\u9393\u76d0\u4e2d\u95f4\u4f53<\/td>\n<td>\u4e0e\u9178\u6027\u8bd5\u5242\u7ed3\u5408\u5f62\u6210\u914d\u5408\u7269<\/td>\n<td>\u63d0\u9ad8\u53cd\u5e94\u6d3b\u6027\u548c\u9009\u62e9\u6027<\/td>\n<\/tr>\n<tr>\n<td>DABCO<\/td>\n<td>\u6c22\u952e\u590d\u5408\u7269<\/td>\n<td>\u4e0e\u4eb2\u6838\u8bd5\u5242\u5f62\u6210\u6c22\u952e\u7edc\u5408<\/td>\n<td>\u4fc3\u8fdb\u4eb2\u6838\u8bd5\u5242\u7684\u8fdb\u653b<\/td>\n<\/tr>\n<tr>\n<td>\u4e09\u4e59\u80fa<\/td>\n<td>\u76d0\u7c7b\u4e2d\u95f4\u4f53<\/td>\n<td>\u4e2d\u548c\u9178\u6027\u526f\u4ea7\u7269\u5f62\u6210\u76d0<\/td>\n<td>\u63a8\u52a8\u53cd\u5e94\u5411\u4ea7\u7269\u65b9\u5411\u8fdb\u884c<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\u8fd9\u4e9b\u4e2d\u95f4\u4f53\u4e0d\u4ec5\u51b3\u5b9a\u4e86\u53cd\u5e94\u7684\u8def\u5f84\uff0c\u8fd8\u76f4\u63a5\u5f71\u54cd\u7ec8\u4ea7\u7269\u7684\u6536\u7387\u548c\u7eaf\u5ea6\u3002\u4f8b\u5982\uff0c\u5728\u4e0d\u5bf9\u79f0Aldol\u53cd\u5e94\u4e2d\uff0c\u812f\u6c28\u9178\u4e0e\u919b\u5f62\u6210\u7684\u4e9a\u80fa\u4e2d\u95f4\u4f53\u53ef\u4ee5\u6709\u6548\u63a7\u5236\u7acb\u4f53\u5316\u5b66\uff0c\u4ece\u800c\u83b7\u5f97\u9ad8ee\u503c\u7684\u4ea7\u7269\u3002<\/p>\n<hr \/>\n<h3>\u56db\u3001\u50ac\u5316\u5242\u7684\u201c\u6c5f\u6e56\u6392\u540d\u201d\u2014\u2014\u8c01\u624d\u662f\u771f\u6b63\u7684\u201c\u50ac\u5316\u5927\u5e08\u201d\uff1f<\/h3>\n<p>\u6211\u4eec\u4e0d\u59a8\u6765\u4e00\u573a\u201c\u6709\u673a\u80fa\u50ac\u5316\u5242\u64c2\u53f0\u8d5b\u201d\uff0c\u770b\u770b\u5b83\u4eec\u5728\u4e0d\u540c\u7ef4\u5ea6\u7684\u8868\u73b0\u5982\u4f55\uff1a<\/p>\n<table>\n<thead>\n<tr>\n<th>\u50ac\u5316\u5242<\/th>\n<th>\u6d3b\u6027<\/th>\n<th>\u9009\u62e9\u6027<\/th>\n<th>\u6210\u672c<\/th>\n<th>\u7a33\u5b9a\u6027<\/th>\n<th>\u73af\u4fdd\u6027<\/th>\n<th>\u7efc\u5408\u8bc4\u5206\uff08\u6ee1\u52065\u661f\uff09<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u4e09\u4e59\u80fa<\/td>\n<td>\u2605\u2605\u2606\u2606\u2606<\/td>\n<td>\u2605\u2605\u2606\u2606\u2606<\/td>\n<td>\u2605\u2605\u2605\u2605\u2605<\/td>\n<td>\u2605\u2605\u2605\u2605\u2606<\/td>\n<td>\u2605\u2605\u2605\u2606\u2606<\/td>\n<td>\u2605\u2605\u2605\u2606\u2606<\/td>\n<\/tr>\n<tr>\n<td>DABCO<\/td>\n<td>\u2605\u2605\u2605\u2605\u2606<\/td>\n<td>\u2605\u2605\u2605\u2606\u2606<\/td>\n<td>\u2605\u2605\u2605\u2606\u2606<\/td>\n<td>\u2605\u2605\u2605\u2605\u2605<\/td>\n<td>\u2605\u2605\u2605\u2605\u2606<\/td>\n<td>\u2605\u2605\u2605\u2605\u2606<\/td>\n<\/tr>\n<tr>\n<td>\u5421\u5576<\/td>\n<td>\u2605\u2605\u2605\u2605\u2606<\/td>\n<td>\u2605\u2605\u2605\u2606\u2606<\/td>\n<td>\u2605\u2605\u2605\u2605\u2606<\/td>\n<td>\u2605\u2605\u2605\u2606\u2606<\/td>\n<td>\u2605\u2605\u2606\u2606\u2606<\/td>\n<td>\u2605\u2605\u2605\u2606\u2606<\/td>\n<\/tr>\n<tr>\n<td>\u812f\u6c28\u9178<\/td>\n<td>\u2605\u2605\u2605\u2606\u2606<\/td>\n<td>\u2605\u2605\u2605\u2605\u2605<\/td>\n<td>\u2605\u2605\u2605\u2606\u2606<\/td>\n<td>\u2605\u2605\u2605\u2606\u2606<\/td>\n<td>\u2605\u2605\u2605\u2605\u2605<\/td>\n<td>\u2605\u2605\u2605\u2605\u2606<\/td>\n<\/tr>\n<tr>\n<td>TBD<\/td>\n<td>\u2605\u2605\u2605\u2605\u2605<\/td>\n<td>\u2605\u2605\u2605\u2605\u2606<\/td>\n<td>\u2605\u2605\u2606\u2606\u2606<\/td>\n<td>\u2605\u2605\u2605\u2606\u2606<\/td>\n<td>\u2605\u2605\u2605\u2606\u2606<\/td>\n<td>\u2605\u2605\u2605\u2605\u2606<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\u4ece\u8868\u683c\u53ef\u4ee5\u770b\u51fa\uff0c\u6ca1\u6709\u54ea\u4e2a\u50ac\u5316\u5242\u662f\u201c\u5168\u80fd\u51a0\u519b\u201d\uff0c\u5b83\u4eec\u5404\u6709\u5343\u79cb\u3002\u9009\u62e9\u65f6\u9700\u6839\u636e\u53cd\u5e94\u7c7b\u578b\u3001\u5e95\u7269\u7279\u6027\u3001\u73af\u5883\u8981\u6c42\u7b49\u7efc\u5408\u8003\u8651\u3002<\/p>\n<hr \/>\n<h3>\u4e94\u3001\u50ac\u5316\u5242\u7684\u201c\u672a\u6765\u4e4b\u8def\u201d\u2014\u2014\u7eff\u8272\u4e0e\u9ad8\u6548\u5e76\u91cd<\/h3>\n<p>\u968f\u7740\u7eff\u8272\u5316\u5b66\u7406\u5ff5\u7684\u6df1\u5165\u4eba\u5fc3\uff0c\u6709\u673a\u80fa\u50ac\u5316\u5242\u56e0\u5176\u4f4e\u6bd2\u3001\u6613\u56de\u6536\u3001\u53ef\u518d\u751f\u7b49\u4f18\u70b9\uff0c\u6b63\u9010\u6b65\u53d6\u4ee3\u4f20\u7edf\u91d1\u5c5e\u50ac\u5316\u5242\u3002<\/p>\n<p>\u8fd1\u5e74\u6765\uff0c\u7814\u7a76\u8005\u4eec\u4e5f\u5728\u4e0d\u65ad\u4f18\u5316\u7ed3\u6784\uff0c\u5f00\u53d1\u65b0\u578b\u6709\u673a\u80fa\u50ac\u5316\u5242\uff0c\u5982\uff1a<\/p>\n<ul>\n<li><strong>\u529f\u80fd\u5316\u79bb\u5b50\u6db2\u4f53\u80fa\u50ac\u5316\u5242<\/strong>\uff1a\u517c\u5177\u79bb\u5b50\u6db2\u4f53\u548c\u6709\u673a\u80fa\u4f18\u70b9\uff0c\u50ac\u5316\u6548\u7387\u9ad8\uff0c\u6613\u4e8e\u56de\u6536\u3002<\/li>\n<li><strong>\u805a\u5408\u7269\u8d1f\u8f7d\u6709\u673a\u80fa<\/strong>\uff1a\u56fa\u5b9a\u5728\u9ad8\u5206\u5b50\u8f7d\u4f53\u4e0a\uff0c\u4fbf\u4e8e\u5de5\u4e1a\u5316\u5e94\u7528\u3002<\/li>\n<li><strong>\u624b\u6027\u80fa\u50ac\u5316\u5242\u7684\u591a\u529f\u80fd\u5316<\/strong>\uff1a\u5982\u53cc\u529f\u80fd\u812f\u6c28\u9178\u50ac\u5316\u5242\uff0c\u53ef\u540c\u65f6\u63d0\u4f9b\u6c22\u952e\u548c\u624b\u6027\u63a7\u5236\u3002<\/li>\n<\/ul>\n<p>\u8fd9\u4e9b\u65b0\u578b\u50ac\u5316\u5242\u4e0d\u4ec5\u63d0\u5347\u4e86\u50ac\u5316\u6548\u7387\uff0c\u4e5f\u62d3\u5bbd\u4e86\u5e94\u7528\u9886\u57df\uff0c\u4e3a\u672a\u6765\u7684\u6709\u673a\u5408\u6210\u6ce8\u5165\u4e86\u65b0\u7684\u6d3b\u529b\u3002<\/p>\n<hr \/>\n<h3>\u516d\u3001\u7ed3\u8bed\uff1a\u6709\u673a\u80fa\u50ac\u5316\u5242\u7684\u6c5f\u6e56\uff0c\u4e0d\u6b62\u4e8e\u4eca\u5929<\/h3>\n<p>\u6709\u673a\u80fa\u50ac\u5316\u5242\u867d\u4e0d\u4f3c\u91d1\u5c5e\u90a3\u822c\u201c\u9ad8\u8c03\u201d\uff0c\u5374\u4ee5\u5176\u6e29\u548c\u3001\u9ad8\u6548\u3001\u73af\u4fdd\u7684\u7279\u6027\uff0c\u5728\u6709\u673a\u5408\u6210\u4e2d\u626e\u6f14\u7740\u8d8a\u6765\u8d8a\u91cd\u8981\u7684\u89d2\u8272\u3002\u4ece\u7b80\u5355\u7684\u4e09\u4e59\u80fa\u5230\u590d\u6742\u7684\u624b\u6027\u812f\u6c28\u9178\uff0c\u6bcf\u4e00\u79cd\u50ac\u5316\u5242\u90fd\u6709\u5176\u72ec\u7279\u7684\u201c\u6027\u683c\u201d\u548c\u201c\u672c\u9886\u201d\u3002<\/p>\n<p>\u672a\u6765\u7684\u50ac\u5316\u5242\u6c5f\u6e56\uff0c\u5fc5\u7136\u662f\u591a\u5143\u5171\u5b58\u3001\u767e\u82b1\u9f50\u653e\u7684\u65f6\u4ee3\u3002\u65e0\u8bba\u4f60\u662f\u5b9e\u9a8c\u5ba4\u7684\u201c\u5c0f\u9505\u7096\u201d\uff0c\u8fd8\u662f\u5de5\u4e1a\u754c\u7684\u201c\u5927\u9505\u716e\u201d\uff0c\u90fd\u80fd\u5728\u6709\u673a\u80fa\u50ac\u5316\u5242\u4e2d\u627e\u5230\u9002\u5408\u81ea\u5df1\u7684\u90a3\u4e00\u6b3e\u3002<\/p>\n<hr \/>\n<h3>\u53c2\u8003\u6587\u732e\uff08\u56fd\u5185\u5916\u8457\u540d\u6587\u732e\u63a8\u8350\uff09\uff1a<\/h3>\n<ol>\n<li><strong>List, B.<\/strong> et al. <em>J. Am. Chem. Soc.<\/em>, 2000, 122, 2395\u20132396.\uff08\u812f\u6c28\u9178\u50ac\u5316\u7684Aldol\u53cd\u5e94\uff09<\/li>\n<li><strong>MacMillan, D. W. C.<\/strong> <em>Nature<\/em>, 2008, 455, 304\u2013308.\uff08\u6709\u673a\u50ac\u5316\u5728\u4e0d\u5bf9\u79f0\u5408\u6210\u4e2d\u7684\u5e94\u7528\uff09<\/li>\n<li><strong>C\u00f3rdova, A.<\/strong> <em>Chem. Rev.<\/em>, 2003, 103, 2597\u20132629.\uff08\u6709\u673a\u80fa\u50ac\u5316\u5242\u5728\u4e0d\u5bf9\u79f0\u53cd\u5e94\u4e2d\u7684\u7814\u7a76\u8fdb\u5c55\uff09<\/li>\n<li><strong>Zhou, J.<\/strong> et al. <em>Org. Lett.<\/em>, 2015, 17, 5436\u20135439.\uff08TBD\u5728\u916f\u4ea4\u6362\u53cd\u5e94\u4e2d\u7684\u5e94\u7528\uff09<\/li>\n<li><strong>Liu, X.<\/strong> et al. <em>Green Chemistry<\/em>, 2020, 22, 3456\u20133468.\uff08\u7eff\u8272\u6709\u673a\u80fa\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u4e0e\u5e94\u7528\uff09<\/li>\n<li><strong>Ooi, T.<\/strong> et al. <em>Angew. Chem. Int. Ed.<\/em>, 2004, 43, 4092\u20134096.\uff08\u624b\u6027\u80fa\u50ac\u5316\u5242\u7684\u4e0d\u5bf9\u79f0\u8bf1\u5bfc\u673a\u5236\uff09<\/li>\n<li><strong>Zhang, W.<\/strong> et al. <em>ACS Catalysis<\/em>, 2019, 9, 1001\u20131012.\uff08DABCO\u5728\u4eb2\u6838\u52a0\u6210\u4e2d\u7684\u50ac\u5316\u673a\u7406\u7814\u7a76\uff09<\/li>\n<li><strong>Bach, T.<\/strong> et al. <em>Eur. J. Org. Chem.<\/em>, 2002, 2002, 3051\u20133066.\uff08\u6709\u673a\u80fa\u5728\u5149\u50ac\u5316\u4e2d\u7684\u534f\u540c\u4f5c\u7528\uff09<\/li>\n<\/ol>\n<hr \/>\n<p>\u613f\u4f60\u5728\u6709\u673a\u5408\u6210\u7684\u5f81\u9014\u4e2d\uff0c\u627e\u5230\u5c5e\u4e8e\u4f60\u7684\u201c\u50ac\u5316\u5242\u826f\u4f34\u201d\uff0c\u4e00\u8def\u50ac\u5316\uff0c\u4e00\u8def\u7cbe\u5f69\uff01<\/p>\n<h2>====================\u8054\u7cfb\u4fe1\u606f=====================<\/h2>\n<h2>\u8054\u7cfb\u4eba\uff1a \u5434\u7ecf\u7406<\/h2>\n<h2>\u624b\u673a\u53f7\u7801\uff1a 18301903156 (\u5fae\u4fe1\u540c\u53f7)<\/h2>\n<h2>\u8054\u7cfb\u7535\u8bdd\uff1a 021-51691811<\/h2>\n<h2>\u516c\u53f8\u5730\u5740: \u4e0a\u6d77\u5e02\u5b9d\u5c71\u533a\u6dde\u5174\u897f\u8def258\u53f7<\/h2>\n<p>===========================================================<\/p>\n<h2>\u805a\u6c28\u916f\u9632\u6c34\u6d82\u6599\u50ac\u5316\u5242\u76ee\u5f55<\/h2>\n<ul>\n<li>\n<h3>NT CAT 680 \u51dd\u80f6\u578b\u50ac\u5316\u5242\uff0c\u662f\u4e00\u79cd\u73af\u4fdd\u578b\u91d1\u5c5e\u590d\u5408\u50ac\u5316\u5242\uff0c\u4e0d\u542bRoHS\u6240\u9650\u5236\u7684\u591a\u6eb4\u8054\u3001\u591a\u6eb4\u4e8c\u919a\u3001\u94c5\u3001\u6c5e\u3001\u9549\u7b49\u3001\u8f9b\u57fa\u9521\u3001\u4e01\u57fa\u9521\u3001\u57fa\u9521\u7b49\u4e5d\u7c7b\u6709\u673a\u9521\u5316\u5408\u7269\uff0c\u9002\u7528\u4e8e\u805a\u6c28\u916f\u76ae\u9769\u3001\u6d82\u6599\u3001\u80f6\u9ecf\u5242\u4ee5\u53ca\u7845\u6a61\u80f6\u7b49\u3002<\/h3>\n<\/li>\n<li>\n<h3>NT CAT C-14 \u5e7f\u6cdb\u5e94\u7528\u4e8e\u805a\u6c28\u916f\u6ce1\u6cab\u3001\u5f39\u6027\u4f53\u3001\u80f6\u9ecf\u5242\u3001\u5bc6\u5c01\u80f6\u548c\u5ba4\u6e29\u56fa\u5316\u6709\u673a\u7845\u4f53\u7cfb\uff1b<\/h3>\n<\/li>\n<li>\n<h3>NT CAT C-15 \u9002\u7528\u4e8e\u82b3\u9999\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u4e2d\u7b49\u50ac\u5316\u6d3b\u6027\uff0c\u6bd4A-14\u6d3b\u6027\u4f4e\uff1b<\/h3>\n<\/li>\n<li>\n<h3>NT CAT C-16 \u9002\u7528\u4e8e\u82b3\u9999\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u5177\u6709\u5ef6\u8fdf\u4f5c\u7528\u548c\u4e00\u5b9a\u7684\u8010\u6c34\u89e3\u6027\uff0c\u7ec4\u5408\u6599\u50a8\u5b58\u65f6\u95f4\u957f\uff1b<\/h3>\n<\/li>\n<li>\n<h3>NT CAT C-128 \u9002\u7528\u4e8e\u805a\u6c28\u916f\u53cc\u7ec4\u4efd\u5feb\u901f\u56fa\u5316\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u5728\u8be5\u7cfb\u5217\u50ac\u5316\u5242\u4e2d\u50ac\u5316\u6d3b\u6027\u5f3a\uff0c\u7279\u522b\u9002\u5408\u7528\u4e8e\u8102\u80aa\u65cf\u5f02\u6c30\u9178\u916f\u4f53\u7cfb\uff1b<\/h3>\n<\/li>\n<li>\n<h3>NT CAT C-129 \u9002\u7528\u4e8e\u82b3\u9999\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u5177\u6709\u5f88\u5f3a\u7684\u5ef6\u8fdf\u6548\u679c\uff0c\u4e0e\u6c34\u7684\u7a33\u5b9a\u6027\u8f83\u5f3a\uff1b<\/h3>\n<\/li>\n<li>\n<h3>NT CAT C-138 \u9002\u7528\u4e8e\u82b3\u9999\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u4e2d\u7b49\u50ac\u5316\u6d3b\u6027\uff0c\u826f\u597d\u7684\u6d41\u52a8\u6027\u548c\u8010\u6c34\u89e3\u6027\uff1b<\/h3>\n<\/li>\n<li>\n<h3>NT CAT C-154 \u9002\u7528\u4e8e\u8102\u80aa\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u5177\u6709\u5ef6\u8fdf\u4f5c\u7528\uff1b<\/h3>\n<\/li>\n<li>\n<h3>NT CAT C-159 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\u4e8c\u6708\u6842\u9178\u4e8c\u4e01\u57fa\u9521\uff0c\u51dd\u80f6\u578b\u50ac\u5316\u5242\uff0c\u9002\u7528\u4e8e\u805a\u919a\u578b\u9ad8\u5bc6\u5ea6\u7ed3\u6784\u6ce1\u6cab\uff0c\u8fd8\u7528\u4e8e\u805a\u6c28\u916f\u6d82\u6599\u3001\u5f39\u6027\u4f53\u3001\u80f6\u9ecf\u5242\u3001\u5ba4\u6e29\u56fa\u5316\u7845\u6a61\u80f6\u7b49\uff1b<\/h3>\n<\/li>\n<li>\n<h3>NT CAT T-125 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